| Matches by round |
| 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 |
| Match list: | By round By date Latest | Player stats: | Cards All players |
| R | Date | Home | Score | Away | HT | >2.5 | HT | FT | |
| 1 | 8/18/2019 | Alaves | 1 - 0 | Levante | 0-0 | No | X | 1 | |
| 2 | 8/25/2019 | Alaves | 0 - 0 | Espanyol | 0-0 | No | X | X | |
| 3 | 8/31/2019 | Getafe | 1 - 1 | Alaves | 1-1 | No | X | X | |
| 4 | 9/15/2019 | Alaves | 0 - 1 | Sevilla | 0-1 | No | 2 | 2 | |
| 5 | 9/22/2019 | Athletic Bilbao | 2 - 0 | Alaves | 1-0 | No | 1 | 1 | |
| 6 | 9/26/2019 | Real Sociedad | 3 - 0 | Alaves | 3-0 | Yes | 1 | 1 | |
| 7 | 9/29/2019 | Alaves | 2 - 0 | Mallorca | 0-0 | No | X | 1 | |
| 8 | 10/5/2019 | Valencia | 2 - 1 | Alaves | 1-0 | Yes | 1 | 1 | |
| 9 | 10/20/2019 | Alaves | 2 - 0 | Celta Vigo | 0-0 | No | X | 1 | |
| 10 | 10/25/2019 | Villarreal | 4 - 1 | Alaves | 1-0 | Yes | 1 | 1 | |
| 11 | 10/29/2019 | Alaves | 1 - 1 | Atletico Madrid | 0-0 | No | X | X | |
| 12 | 11/3/2019 | Osasuna | 4 - 2 | Alaves | 3-1 | Yes | 1 | 1 | |
| 13 | 11/9/2019 | Alaves | 3 - 0 | Real Valladolid | 2-0 | Yes | 1 | 1 | |
| 14 | 11/24/2019 | Eibar | 0 - 2 | Alaves | 0-0 | No | X | 2 | |
| 15 | 11/30/2019 | Alaves | 1 - 2 | Real Madrid | 0-0 | Yes | X | 2 | |
| 16 | 12/7/2019 | Granada | 3 - 0 | Alaves | 0-0 | Yes | X | 1 | |
| 17 | 12/13/2019 | Alaves | 1 - 1 | Leganes | 0-1 | No | 2 | X | |
| 18 | 12/21/2019 | Barcelona | 4 - 1 | Alaves | 2-0 | Yes | 1 | 1 | |
| 19 | 1/5/2020 | Alaves | 1 - 1 | Real Betis | 1-0 | No | 1 | X | |
| 20 | 1/18/2020 | Levante | 0 - 1 | Alaves | 0-0 | No | X | 2 | |
| 21 | 1/25/2020 | Alaves | 1 - 2 | Villarreal | 0-1 | Yes | 2 | 2 | |
| 22 | 2/2/2020 | Sevilla | 1 - 1 | Alaves | 0-0 | No | X | X | |
| 23 | 2/7/2020 | Alaves | 2 - 1 | Eibar | 0-0 | Yes | X | 1 | |
| 24 | 2/15/2020 | Mallorca | 1 - 0 | Alaves | 0-0 | No | X | 1 | |
| 25 | 2/23/2020 | Alaves | 2 - 1 | Athletic Bilbao | 1-1 | Yes | X | 1 | |
| 26 | 2/29/2020 | Leganes | 1 - 1 | Alaves | 0-0 | No | X | X | |
| 27 | 3/6/2020 | Alaves | 1 - 1 | Valencia | 0-1 | No | 2 | X | |
| 28 | 6/13/2020 | Espanyol | 2 - 0 | Alaves | 1-0 | No | 1 | 1 | |
| 29 | 6/18/2020 | Alaves | 2 - 0 | Real Sociedad | 0-0 | No | X | 1 | |
| 30 | 6/21/2020 | Celta Vigo | 6 - 0 | Alaves | 4-0 | Yes | 1 | 1 | |
| 31 | 6/24/2020 | Alaves | 0 - 1 | Osasuna | 0-0 | No | X | 2 | |
| 32 | 6/27/2020 | Atletico Madrid | 2 - 1 | Alaves | 0-0 | Yes | X | 1 | |
| 33 | 7/1/2020 | Alaves | 0 - 2 | Granada | 0-1 | No | 2 | 2 | |
| 34 | 7/4/2020 | Real Valladolid | 1 - 0 | Alaves | 0-0 | No | X | 1 | |
| 35 | 7/10/2020 | Real Madrid | 2 - 0 | Alaves | 1-0 | No | 1 | 1 | |
| 36 | 7/13/2020 | Alaves | 0 - 0 | Getafe | 0-0 | No | X | X | |
| 37 | 7/16/2020 | Real Betis | 1 - 2 | Alaves | 0-0 | Yes | X | 2 | |
| 38 | 7/19/2020 | Alaves | 0 - 5 | Barcelona | 0-3 | Yes | 2 | 2 |